Preparation of a Composite of Copper Oxide Nanoparticles with Carbon by Exploding Graphite Rod in Aqueous Suspension

Main Article Content

Sawsan H. Abdulla
Hammad R. Humud
Falah I. Mustafa

Abstract

In this work, the effect of preparing a composite of copper oxide nanoparticles with carbon on some of its optical properties was studied. The composite preparing process was carried out by exploding graphite electrodes in an aqueous suspension of copper oxide. The properties of the plasma which is formed during the explosion were studied using emission spectroscopy in order to determine the most important elements that are present in the media. The electron’s density and their energy, which is the main factor in the composite process, were determined. The particle properties were studied before and after the exploding process. The XRD showed an additional peak in the copper oxides pattern corresponding to the hexagonal graphite structure for the composite. The UV-visible absorbance for the composite was significantly enhanced. The direct bandgap decreased from 2.55 to 2.4 eV, and the indirect bandgap decreased from 1.1 to 1 eV, for the composite.

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How to Cite
1.
Abdulla SH, Humud HR, Mustafa FI. Preparation of a Composite of Copper Oxide Nanoparticles with Carbon by Exploding Graphite Rod in Aqueous Suspension. IJP [Internet]. 2022 Mar. 1 [cited 2024 Dec. 22];20(1):26-3. Available from: https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/961
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References

Fikry M., Tawfik W., and Omar M.M., Investigation on the effects of laser parameters on the plasma profile of copper using picosecond laser induced plasma spectroscopy. Optical Quantum Electronics, 2020. 52(5): pp. 1-16.

Tu B., Li M., Lu Q., Yang Y., Yao K., Lu D., Shen Y., Chen C., Hutton R., and Zou Y., Simulating a low-temperature Maxwellian plasma using SH-HtscEBIT. Physics Letters A, 2018. 382(37): pp. 2673-2676.

Hamed S., Spectroscopic determination of excitation temperature and electron density in premixed laminar flame. Egypt. J. Solids, 2005. 28(2): pp. 349-357.

Stambulchik E., Kroupp E., Maron Y., and Malka V., On the Stark Effect of the OI 777-nm Triplet in Plasma and Laser Fields. J Atoms, 2020. 8(84): pp. 1-9.

Ni S., Chen Y., Li C., Zhang Z., Ning H., Kong X., Wang B., and Hosseinpour M., Plasma emission induced by electron cyclotron maser instability in solar plasmas with a large ratio of plasma frequency to gyrofrequency. The Astrophysical Journal Letters, 2020. 891(1): pp. 1-8.

Khabarov K., Nouraldeen M., Tichonov S., Lizunova A., Efimov A., and Ivanov V., Modification of Aerosol Gold Nanoparticles by Nanosecond Pulsed-Periodic Laser Radiation. Nanomaterials, 2021. 11(10): pp. 1-19.

Wasfi A.S., Humud H.R., and Fadhil N.K., Synthesis of core-shell Fe3O4-Au nanoparticles by electrical exploding wire technique combined with laser pulse shooting. Optics Laser Technology, 2019. 111: pp. 720-726.

Bien T., Gu W., Bac L., and Kim J., Preparation and characterization of copper-graphite composites by electrical explosion of wire in liquid. Journal of Nanoscience Nanotechnology, 2014. 14(11): pp. 8750-8755.

Kang J., Kim Y., Kim H.-m., Hu X., Saito N., Choi J.-H., and Lee M.-H., In-situ one-step synthesis of carbon-encapsulated naked magnetic metal nanoparticles conducted without additional reductants and agents. Scientific reports, 2016. 6(1): pp. 1-9.

Gao X., Xu C., Yin H., Wang X., Song Q., and Chen P., Preparation of graphene by electrical explosion of graphite sticks. Nanoscale, 2017. 9(30): pp. 10639-10646.

Bragg W.H. and Bragg W.L., X rays and crystal structure. 1918: G. Bell.

Scherrer P., Göttinger Nachrichten. Universität zu Göttingen, 1918. 2: pp. 98-102.

Wang F., Liang L., Shi L., Liu M., and Sun J., CO2-assisted synthesis of mesoporous carbon/C-doped ZnO composites for enhanced photocatalytic performance under visible light. Dalton Transactions, 2014. 43(43): pp. 16441-16449.

Ding X., Zeng D., Zhang S., and Xie C., C-doped WO3 microtubes assembled by nanoparticles with ultrahigh sensitivity to toluene at low operating temperature. Sensors Actuators B: Chemical, 2011. 155(1): pp. 86-92.

Chen M.X., Zhu M., Zuo M., Chu S.Q., Zhang J., Wu Y., Liang H.W., and Feng X., Identification of catalytic sites for oxygen reduction in metal/nitrogen‐doped carbons with encapsulated metal nanoparticles. Angewandte Chemie, 2020. 132(4): pp. 1644-1650.

Sahai A., Goswami N., Kaushik S., and Tripathi S., Cu/Cu2O/CuO nanoparticles: Novel synthesis by exploding wire technique and extensive characterization. Applied Surface Science, 2016. 390: pp. 974-983.

Shibkov V., Shibkova L., and Logunov A., The electron temperature in the plasma of a dc discharge created in a supersonic airflow. Moscow University Physics Bulletin, 2017. 72(3): pp. 294-300.

Mijatović Z., Djurović S., Gavanski L., Gajo T., Favre A., Morel V., and Bultel A., Plasma density determination by using hydrogen Balmer Hα spectral line with improved accuracy. Spectrochimica Acta Part B: Atomic Spectroscopy, 2020. 166: pp. 1-8.

NIST Atomic Spectra Database. http://kinetics.nist.gov/index.php.

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