Effect of Zinc (Zn) -Doped on the Structural, Optical and Electrical Properties of (Cdo)1-Xznx Films Prepared by Pulsed Laser Deposition Technique
Main Article Content
Abstract
Pure cadmium oxide films (CdO) and doped with zinc were prepared at different atomic ratios using a pulsed laser deposition technique using an ND-YAG laser from the targets of the pressed powder capsules. X-ray diffraction measurements showed a cubic-shaped of CdO structure. Another phase appeared, especially in high percentages of zinc, corresponding to the hexagonal structure of zinc. The degree of crystallinity, as well as the crystal size, increased with the increase of the zinc ratio for the used targets. The atomic force microscopy measurements showed that increasing the dopant percentage leads to an increase in the size of the nanoparticles, the particle size distribution was irregular and wide, in addition, to increase the surface roughness of the nanoparticles. An increase in the zinc ratio also led to a decrease in the energy gap. While the Hall effect measuring showed an increase in the concentration of charge carriers and a decrease in their mobility with increasing the doping ratio.
Article Details
This work is licensed under a Creative Commons Attribution 4.0 International License.
© 2023 The Author(s). Published by College of Science, University of Baghdad. This is an open-access article distributed under the terms of the Creative Commons Attribution 4.0 International License.
References
Alemi, A., Joo, S.W., Khademinia, S., Dolatyari, M., and Bakhtiari, A., Sol – gel synthesis , characterization, and optical properties of Gd3+ -doped CdO sub-micron materials. International Nano Letters, 2013. 3(3): pp. 2–7.
Minami, T., Transparent conducting oxide semiconductors for transparent electrodes. Semiconductor Science and Technology, 2005. 20(4): pp. 35–44.
Gokul, B., Matheswaran, P., and Sathyamoorthy, R., Influence of Annealing on Physical Properties of CdO Thin Films Prepared by SILAR Method. Journal of Materials Science and Technology,2013. 29(1): pp. 17–21.
Zaien, M., Ahmed, N.M., and Hassan, Z., Fabrication and characterization of an n-CdO/p-Si solar cell by thermal evaporation in a vacuum. International Journal of Electrochemical Science, 2013. 8(5): pp. 6988–6996.
Murbat, H.H., Abdalameer, N.K., Kh. Brrd, A., and Abdulameer, F., Effects of Non-Thermal Argon Plasma Produced at Atmospheric Pressure on the Optical Properties of CdO Thin Films. Baghdad Science Journal, 2018. 15(2): pp. 221–226.
Siraj, K., Khaleeq-Ur-Rahman, M., Hussain, S.I., Rafique, M.S., and Anjum, S., Effect of deposition temperature on structural, surface, optical and magnetic properties of pulsed laser deposited Al-doped CdO thin films. Journal of Alloys and Compounds, 2011. 509(24): pp. 6756–6762.
Usharani, K., and Balu, A.R., Structural, optical, and electrical properties of Zn-doped CdO thin films fabricated by a simplified spray pyrolysis technique. Acta Metallurgica Sinica (English Letters), 2015. 28(1): pp. 64–71.
Koole, R., Groeneveld, E., and Daniel Vanmaekelbergh, Nanoparticles: Workhorses of nanoscience, Springer-Verlag Berlin Heidelberg, Utrecht, The Netherlands, 2014.
Chandiramouli, R., and Jeyaprakash, B.G., Review of CdO thin films. Solid State Sciences, 2013. 16: pp. 102–110.
Bragg, W.H., and Bragg, W.L., X Rays and Crystal Structure, G. Bell and Sons, LTD., London, 1918.
P. Scherrer, Göttinger Nachrichten Gesell. Universität zu Göttingen, 1918. 2: pp. 98-100.
Beukes, P., and Maaza, M., Green synthesis of Monteponite CdO nanoparticles by Agathosma betulina natural extract. Journal of Alloys and Compounds, 2015. 646: pp. 1043–1048.
Calnan, S., Applications of Oxide Coatings in Photovoltaic Devices. Coatings, 2014. 4(1): pp. 162–202.
Mututu, V., Sunitha, A.K., Thomas, R., Pandey, M., and Manoj, B., An investigation on structural, electrical and optical properties of GO/ZnO nanocomposite. International Journal of Electrochemical Science, 2019. 14(4): pp. 3752–3763.
Yahia, I.S., Salem, G.F., Iqbal, J., and Yakuphanoglu, F., Linear and nonlinear optical discussions of nanostructured Zn-doped CdO thin films. Physica B: Condensed Matter, 2017. 511: pp. 54–60.
Manjula, N., Suganya, M., Prabha, D., Balamurugan, S., Srivind, J., Nagarethinam, V. S., and Balu, A. R., Optoelectronic, magnetic and antibacterial properties of CdO thin films doubly doped with Mn (cationic) and F (anionic) ions. Journal of Materials Science: Materials in Electronics, 2017. 28(11): pp. 7615–7621.
Gibbs, Z.M., Lalonde, A., and Snyder, G.J., Optical band gap and the Burstein-Moss effect in iodine doped PbTe using diffuse reflectance infrared Fourier transform spectroscopy. New Journal of Physics, 2013. 15: pp. 1–18.
Jin, S., Yang, Y., Medvedeva, J.E., Ireland, J., Metz, A., Ni, J., Kannewurf, C., Freeman, A., and Marks, T., Dopant ion size and electronic structure effects on transparent conducting oxides. Sc-doped CdO thin films grown by MOCVD. Journal of the American Chemical Society, 2004. 126(42): pp. 13787–13793.
Bel-Hadj-Tahar, R., and Mohamed, A.B., Sol-Gel Processed Indium-Doped Zinc Oxide Thin Films and Their Electrical and Optical Properties. New Journal of Glass and Ceramics, 2014. 4: pp. 55–65.