Corrosion Protection Performance of PACC and PACC-Metal Oxides Nanocomposites Electropolymerized Coating of Low Carbon Steel

Main Article Content

Zainab A. Hussain
Khulood A. Saleh

Abstract

In the current study, a novel conductive polymer poly 6-((4 acetylphenyl) carbamoyl) cyclohex-3-ene-1-carboxylic acid (PACC) was created by polymerized 6-((4 acetylphenyl) carbamoyl) cyclohex-3-ene-1-carboxylic acid (ACC) monomer using the electropolymerization process. The resulting polymer was characterized using Fourier Transform Infrared Spectroscopy (FTIR). The ability of this polymer to protect the alloy from corrosion was studied at temperatures ranging between 298 and 328 K. The ability of these coatings to stop corrosion on the surface was assessed by measuring the corrosion potential (Ecorr) and the corrosion current (icorr) using a potentiostat. Adding nanoscale metal oxides (zirconium dioxide (ZrO2) and magnesium oxides (MgO)) enhanced the efficiency of this polymeric coating. The protection efficiency of the polymer alone was 77.5%; this efficiency increased to 85.0% and 99.7% in the presence of nano ZrO2 and MgO, respectively. Kinetic and thermodynamic parameters (Ea, H, and S) were calculated for uncoated and coated LCS. An atomic force microscope (AFM) studied the coating surface morphology. Electrochemical impedance spectroscopy (EIS) was used to evaluate the coating resistance.

Article Details

How to Cite
1.
Hussain ZA, Saleh KA. Corrosion Protection Performance of PACC and PACC-Metal Oxides Nanocomposites Electropolymerized Coating of Low Carbon Steel. IJP [Internet]. 2024 Jun. 1 [cited 2024 Dec. 3];22(2):90-103. Available from: https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/1213
Section
Articles

References

P. R. Ammal, M. Prajila, and A. Joseph, J. Envir. Chem. Eng. 6, 1072 (2018).

V. Vorobyova, M. Skiba, and E. Gnatko, S. African J. Chem. Eng. 43, 273 (2023).

A. Tenorio-Alfonso, M. C. Sánchez, and J. M. Franco, J. Poly. Envir. 28, 749 (2020).

M. A. Bedair, H. M. Elaryian, E. S. Gad, M. Alshareef, A. H. Bedair, R. M. Aboushahba, and A. E.-a. S. Fouda, RSC Advances 13, 478 (2023).

S. De and J. L. Lutkenhaus, Gre. Chem. 20, 506 (2018).

R. Mohammed and K. Saleh, Eurasian Chem. Commun. 3, 715 (2021).

S. A. Umoren and M. M. Solomon, Prog. Mater. Sci. 104, 380 (2019).

S. Cherdchom, W. Keawsongsaeng, W. Buasorn, N. Rimsueb, P. Pienpinijtham, A. Sereemaspun, R. Rojanathanes, and P. Aramwit, ACS Omega 6, 28880 (2021).

S. Bhadra, D. Khastgir, N. K. Singha, and J. H. Lee, Prog. Poly. Sci. 34, 783 (2009).

U. Saviour, Prog. Mat. Sci. 104, 380 (2019).

B. D. Malhotra, Handbook of Polymers in Electronics (UK, Rapra Technology Limited, 2001).

Y. Samet, D. Kraiem, and R. Abdelhédi, Prog. Org. Coat. 69, 335 (2010).

J. Heinze, B. A. Frontana-Uribe, and S. Ludwigs, Chem. Rev. 110, 4724 (2010).

M. I. Khan, A. U. Chaudhry, S. Hashim, M. K. Zahoor, and M. Z. Iqbal, Chem. Eng. Res. Bull. 14, 73 (2010).

S. El Aggadi, N. Loudiyi, A. Chadil, Z. El Abbassi, and A. El Hourch, Mediterran. J. Chem. 10, 138 (2020).

M. M. Gvozdenović, B. Jugović, J. Stevanović, and B. N. Grgur, Hemij. Indust. 68, 673 (2014).

Y. Jiang, W. Zheng, K. Tran, E. Kamilar, J. Bariwal, H. Ma, and H. Liang, Nat. Commun. 13, 197 (2022).

N. A. Khudhair, A. T. Bader, M. I. Ali, and M. Husseini, AIP Conference Proceedings (Karbala, Iraq AIP Publishing, 2020). p. 030014.

R. A. Mohammed and K. A. Saleh, Chem. Methodol. 6, 74 (2022).

M. I. Ali and K. A. Saleh, IOP Conference Series: Materials Science and Engineering (IOP Publishing, 2019). p. 012072.

R. A. Mohammed and K. A. Saleh, Mater. Today Proce. 61, 805 (2022).

A. Khulood, S. Khalil, and I. Muna, J. Phar. Bio. Sci. 13, 30 (2018).

W. S. Hummers, Jr. and R. E. Offeman, J. American Chem. Soci. 80, 1339 (1958).

A. M. Alqudsi and K. A. Saleh, Baghdad Sci. J. 21, 1243 (2024).

Z. Hussain and K. A Saleh, J. Nanostruc. 13, 718 (2023).

I. M. Mohammed, Baghdad Sci. J. 16, 0049 (2019).

R. L. Shriner, R. Fuson, and D. Y. Curtin, Thesystematic identification of organic compounds (Canada, John Wileyand Sons, Inc, 1948).

K. S. Khalil, K. A. Saleh, and M. I. Khalaf, Int. J. Pharma. Qual. Ass. 9, 253 (2018).

Y. Zhao, Z. Wei, Q. Pang, Y. Wei, Y. Cai, Q. Fu, F. Du, A. Sarapulova, H. Ehrenberg, and B. Liu, ACS Appl. Mater. Inter. 9, 4709 (2017).

K. G. Alves, J. F. Felix, E. F. De Melo, C. G. Dos Santos, C. A. Andrade, and C. P. De Melo, J. Appl. Poly. Sci. 125, E141 (2012).

H. A. Al-Mashhadani and K. A. Saleh, Res. J. Pharm. Tech. 13, 4687 (2020).

R. M. Kubba, M. A. Mohammed, and L. S. Ahamed, Baghdad Sci. J. 18, 0113 (2021).

S. A. Alkhfaji and M. I. Ali, Ibn AL-Haitham J. Pure Appl. Sci. 35, 161 (2022).

M. Molaei, A. Fattah-Alhosseini, M. Nouri, P. Mahmoodi, S. H. Navard, and A. Nourian, Surf. Inter. 30, 101967 (2022).

R. A. Mohammed and K. A. Saleh, Iraqi J. Sci. 63, 4163 (2022).

K. A. Saleh and M. I. Ali, Iraqi J. Sci. 61, 1 (2020).

M. I.Ali and K. A.Saleh, Int. J. Eng. Tech. 7, 5821 (2018).

K. a. K. Al-Rudaini and K. a. S. Al-Saadie, Iraqi J. Sci. 62, 363 (2021).

M. Husaini, B. Usman, and M. B. Ibrahim, Bayero J. Pure Appl. Sci. 11, 88 (2018).

G. K. Gomma and M. H. Wahdan, Mater. Chem. Phys. 39, 209 (1995).

A. J. Huh and Y. J. Kwon, J. Cont. Rel. 156, 128 (2011).

S. A. Umoren, M. J. Banera, T. Alonso-Garcia, C. A. Gervasi, and M. V. Mirífico, Cellulose 20, 2529 (2013).

M. Hosseini, L. Fotouhi, A. Ehsani, and M. Naseri, J. Coll. Inter. Sci. 505, 213 (2017).

A. U. Ammar, M. Shahid, M. K. Ahmed, M. Khan, A. Khalid, and Z. A. Khan, Materials 11, 332 (2018).

T. Ohtsuka, A. Nishikata, M. Sakairi, and K. Fushimi, Electrochemistry for Corrosion Fundamentals (Japan, Springer, 2018).

A. Farhan and N. Kadhim, PhD. Thesis, University of Baghdad, 2018.

B. Javanpour, M. Azadbeh, and M. Mozammel, J. Inorg. Organomet. Poly. Mater. 30, 4082 (2020).

E. Locorotondc, L. Pugi, L. Berzi, M. Pierini, S. Scavuzzc, A. Ferraris, A. G. Airale, and M. Carello, 2019 IEEE 5th International forum on Research and Technology for Society and Industry (RTSI) (Florence, Italy IEEE, 2019). p. 225.

M. Deyab, K. Eddahaoui, R. Essehli, S. Benmokhtar, T. Rhadfi, A. De Riccardis, and G. Mele, J. Molec. Liq. 216, 699 (2016).

Ł. Drewniak and S. Kochowski, J. Mater. Sci. Mater. Elec. 31, 19106 (2020).

Similar Articles

You may also start an advanced similarity search for this article.