Light Generation from PbI2 Nanoparticles Illuminated by a UV Source

Main Article Content

Shahad Jasim Abdul Sahib
Omar Adnan Ibrahim

Abstract

This study investigates the photoluminescence properties of lead iodide (PbI₂) nanoparticles embedded in a polyvinyl alcohol (PVA) matrix when illuminated by ultraviolet (UV) light. The PbI₂ nanoparticles, dispersed uniformly within the PVA polymer matrix, exhibit enhanced stability and efficient light emission due to the protective environment provided by PVA. Upon UV illumination, the PbI₂ nanoparticles generate visible light, with emission characteristics influenced by the nanoparticle size, concentration, and interaction with the PVA matrix. The role of PVA as a stabilizing agent and its effect on the photophysical properties of PbI₂ are analyzed, showing an improvement in quantum efficiency and photostability. This hybrid nanocomposite system demonstrates potential applications in UV-responsive optoelectronic devices, flexible light-emitting materials, and photonic sensors. The study offers ideas about the integration of semiconductor nanoparticles with polymer matrices for advanced light-generation technologies. This study explores the interaction between UV light and PbI₂ nanoparticles, focusing on the photophysical processes that lead to light generation.

Received: Dec. 19, 2024 Revised:  Mar. 21, 2025 Accepted: Apr. 06, 2025

Article Details

Section

Articles

How to Cite

1.
Jasim Abdul Sahib S, Adnan Ibrahim O. Light Generation from PbI2 Nanoparticles Illuminated by a UV Source. IJP [Internet]. 2026 Jun. 1 [cited 2026 Jun. 2];24(2):96-104. Available from: https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/1411

References

1. F. Yan, S. T. Tan, X. Li, and H. V. Demir, NANO MICRO Small, 15, 1902079 (2019). https://doi.org/10.1002/smll.201902079.

2. M. Mączka, J. K. Zaręba, A. Nowok, N. Sokołowski, A. Sieradzki, A. Gągor and M. Ptak, Chem. Mat., 36, 10758 (2024). https://doi.org/10.1021/acs.chemmater.4c02394.

3. T. Webb and S. A. Haque, Energy Environ. Sci., 17, 3244 (2024), https://doi.org/10.1039/D3EE03004K.

4. Y. Zhang, J. Huang, M. Zhu, Z. Zhang, K. Nie, Z. Wang, X. Liao, L. Shu, T. Tian, Z. Wang, Y. Lu and L. Fei, Chem. Sci., 15, 1782 (2024). https://doi.org10.1039/d3sc05434a.

5. 5- S. M. Mohammed, K. H. Amani, J. Phys.: Conf. Ser., 1795, 012019 (2021). https://doi.org10.1088/1742-6596/1795/1/012019.

6. T. Webb and S. A. Haque, Energy Environ. Sci., 17, 3244 (2024). https://doi.org10.1039/D3EE03004K

7. N. G. Adnan and E. K. Hassan, Iraqi J. Phys, 22, 116 (2024). https://doi.org10.30723/ijp.v22i3.1266.

8. A. Bouich, J. Marí-Guaita, B. M. Soucase and P. Palacios, Mater. Res. Bull., 163, 112213 (2023). https://doi.org/10.1016/j.materresbull.2023.112213.

9. P. A. Beckmann, Cryst. Res. Technol., 45, 455 (2010). https://doi.org10.1002/crat.201000066.

10. A. N. Singh, A. Janna, M. Selvaraj, M. A. Asirri, S. Yun, and K. Wan Nam, Nanomaterials, 13, 3049 (2023). https://doi.org10.3390/nano13233049.

11. M. Mączka J. K. Zaręba A. Nowok N. Sokołowski A. Sieradzki A. Gągor, and M. Ptak, Chem. Mat., 36, 10758 (2024). https://doi.org/10.1021/acs.chemmater.4c02394.

12. K. A. Khalaph, Z. J. Shanan, A. M. Jafar, and F. M. Al-Attar, Defect and Diffusion Forum, 398, 140 (2020). https://doi.org/10.4028/www.scientific.net/DDF.398.140.

13. J. M. Guaita A. Bouich, and B. Mari, JOM, 74, 3103 (2022). Doi: https://doi.org/10.1007/s11837-022-05347-4.

14. T. Hattori, T. Taira, M. Era, T. Tsutsui, S. Saito, Chem. Phys. Lett, 254, 103 (1996). https://doi.org/10.1016/0009-2614(96)00310-7.

15. L. Gollino N. Mercier and T. Parport, MDPI, Nanomaterials, 13, (2023) 1245. https://doi.org/10.3390/nano13071245.

16. N. Kumar, J. Rani, and R. Kurchania, Mater. Today: Proceedings, 46, 5570 (2021), https://doi.org/10.1016/j.matpr.2020.09.349.

17. Z. Zheng, S. Wang, Y. Hu, Y. Rong, A. Mei, and H. Han, Chem. Sci., 13, 2167 (2022). https://doi.org/10.1039/D1SC04769H.

18. A. N. Singh, A. Janna, M. Selvaraj, M. A. Asirri, S. Yun, and K. Wan, MDPI, 13 (2023). https://doi.org10.3390/nano13233049.

19. S. Kar, N. F. Jamaludin, N. Yantara, S. G. Mhaisalkar, and W. L. Leong, Nanophotonics, 10, 2103 (2020). https://doi.org/10.1515/nanoph-2021-0033.

20. A. N. Naje, O. A. Ibrahim, and E. T. Abdullah, Iraqi Journal of Science. 64, 12 (2023). https://doi.org10.24996/ijs.2023.64.12.16.

21. H. A. Ashoor and A. A. Mohammed, Iraqi J. Phys, 22, 27 (2024), https://doi.org10.30723/ijp.v22i3.1241.

Similar Articles

You may also start an advanced similarity search for this article.