Investigation of Optical and Electrical properties of Solid Polymer Electrolyte based on Natural polymer
Main Article Content
Abstract
Solid biopolymer electrolytes (SBEs) consisting of a natural blend that is leak-proof, biodegradable, and flexible are widely studied. In this study, an SBE composed of a fixed ratio of 50:50 of chitosan: polyvinylpyrrolidone (CS: PVP), and CS: PVP mixed with potassium iodide (KI) of different weight percentages of 7.5, 15, 22.5, 30, and 37.5 wt.% was prepared using the solution casting technique. The samples were characterized using UV-Vis spectrophotometry, Fourier transform infrared (FTIR), and AC conductivity. FTIR analysis confirmed the interaction between the polymer blend of CS: PVP and the potassium salt. The addition of KI was found to disrupt hydrogen bonding between the polymer chains, likely due to the polymer-salt interaction. Only one absorption peak was observed in the UV-Vis spectroscopy of the sample at around 315 nm. The conductivity increased as the KI wt.% increased, having a value of 3 × 10⁻⁴ S.cm⁻¹ at room temperature for the CS: PVP blend with 37.5 wt.% KI.
Article Details
Issue
Section
This work is licensed under a Creative Commons Attribution 4.0 International License.
© 2023 The Author(s). Published by College of Science, University of Baghdad. This is an open-access article distributed under the terms of the Creative Commons Attribution 4.0 International License.
How to Cite
References
Wu, I.-D. & Chang, Polymer (Guildf) ,48, 989–996 (2007)]. https://doi.org/10.1016/j.polymer.2006.12.045
J Yue, M Yan, YX Yin & YG Guo, Feature Article, 2018, Volume28, Issue38, https://doi.org/10.1002/adfm.201707533
Schnell, J.; Gunther, T.; Knoche, T.; Vieider, C.; Köhler, L.; Just, A.; Keller, M.; Passerini & S.; Reinhart, 2018, 382, 160–175, https://doi.org/10.1016/j.jpowsour.2018.02.062
Janek & WG Zeier, Nature Energy volume 1, Article number: 16141 (2016).
Luhan Ye & Xin Li, Nature 2021, 593, 218–222.
D. Zhang, X. Meng, W. Hou, W. Hu, J. Mo, T. Yang, W. Zhang, Q. Fan, L. Liu, B. Jiang, L. Chu & M. Li, Nano Res, 2023, 2: e9120050, https://doi.org/10.26599/NRE.2023.9120050
S. Karthikeyan, S. Selvasekarapandian, M. Premalatha, S. Monisha, G. Boopathi, G. Aristatil, A. Arun & S. Madeswaran, Springer Nature, Volume 23, pages 2775–2780, (2017)
H Yang, Y Liu, L Kong, L Kang & F Ran. Journal of Power Sources, 2019, Volume 426, Pages 47-54. https://doi.org/10.1016/j.jpowsour.2019.04.023
AZ Naser, I Deiab & BM Darras , DOI: 10.1039/D1RA02390J (Review Article) RSC Adv., 2021, 11, 17151-17196
Ahmed, M.E.; Mohamed, H.M.; Mohamed, M.I.; Kandile, N.G.. and Int. J. Biol. Macromol. 2020, 162, 1388–1397. https://doi.org/10.1016/j.ijbiomac.2020.08.048
A. M. Abdelghany1 · M. S. Meikhail2· A. H. Oraby2 and M. A. Aboelwafa2 (2023) , Vol. 80 , pages 13279–13298, https://doi.org/10.1007/s00289-023-04700-0
Pooja Rawat, R.K. Prajapati, Gulshan Kumar Meena & A.L. Saroj , Volume 308, October 2024, 117603, DOI: https://doi.org/10.1016/j.mseb.2024.117603
H. G. Rauf, J. M. Hadi, S. B. Aziz, R. T. Abdulwahid, and M. S. Mustafa, Int. J. Electrochem. Sci, vol. 17, 2 (2022), https://doi.org/10.20964/2022.05.04
AM Zulkifli, N I A M Said, S Bakr Aziz, EMA Dannoun, S Hisham, S Shah, A Abu Bakar, Z Hazrin Zainal, H Anuar Tajuddin 5, J Mohammed Hadi 7,8, M Ali Brza 9, S Raza Saeed 10 and POmer Amin 10
Molecules, 202010, 2020, 25(18), 4115; https://doi.org/10.3390/molecules25184115.
MK Jawad, SR Majid, EA Al-Ajaj, MH Suhail - Adv. Phys. Theor. Appl, 2014, Vol.29, 2225-0638.
F. F. Awang, M. F. Hassan & K. H. Kamarudin, Springer Nature, Volume 28, pages 1249–1263, (2022)
IA Safo, M Werheid, C Dosche & M Oezaslan, DOI: 10.1039/C9NA00186G (Paper) Nanoscale Adv., 2019, 1, 3095-3106.
L. A. Jassim and M. K. Jawad¹, IRAQI JOURNAL OF APPLIED PHYSICS, Vol. 20, No. 1A, January 2024, pp. 61-66.
K. Deshmukh, M. Ahamed, K. Sadasivuni, D. Ponnamma, M. Al‐Ali A. Rajendra, R. Deshmukh, S. Pasha, A. Polu, & K. Chidambaram , Journal of Applied Polymer Science, vol. 134, no. 5, 2017,
https://doi.org/10.1002/app.44427
JO Dennis, AA Adam, MKM Ali, H Soleimani, MFBA Shukur, KH Ibnaouf, O Aldaghri , M. H. Eisa 4,M. A. Ibrahem 4,Abubakar Bashir Abdulkadir 1,2 and Vipin Cyriac 5 , Membranes 2022, 12(7), 706; https://doi.org/10.3390/membranes12070706
Najlaa J. Abdullah*1, Abbas F. Essa1 and Salma M. Hasan2,2020, , Iraqi Journal of Science, 2021, Vol. 62, No. 1, pp: 138-146. DOI: 10.24996/ijs.2021.62.1.13
AM Abdelghany, MS Meikhailb, AA El-Banab - Global Journal of Physics, 2019 , GJP 9:821–831
Elashmawi, AM Abdelghany & NA Hakeem, Journal of Materials Science, Volume 24, pages 2956–2961, (2013)
M. M. Nofal, J. M. Hadi, S. B. Aziz, M. A. Brza, A. S. Asnawi, E. M. Dannoun, A. M. Abdullah, and M. F. Kadir, Materials , 14, 4859 (2021). https://doi.org/10.3390/ma14174859
M. K. Jawad and F. M. Ahmed, (2024), polymer, Vol. 20, No. 1A, 2024, pp. 43-50.
Sh. M. Abdulkareem and M. K. Jawad, Iraqi Journal of Physics, 2019, Vol.17, No.42, PP. 42-50, DOI: 10.20723/ijp.17.42.42-50
M.K. Jawad1* and Abdulkareem M.A. Alsammarraie2, Indian Journal of Natural Sciences, Vol. 9 / Issue 50 /October 2018.