Water Treatment Performance of PAN/HPMC/Gr Nano Composites
Main Article Content
Abstract
This study investigates polyacrylonitrile:hydroxypropyl methylcellulose )PAN:HPMC( and PAN:HPMC: graphene (Gr) composite nanofibers prepared using the electrospinning technique. Electrospinning is a simple and versatile technique that relies on the electrostatic repulsion between surface charges to continuously draw nanofibers from a viscoelastic fluid. Membrane technology is vital in removing contaminants due to its easy handling and high efficiency. The results demonstrated that the Gr was successfully incorporated into the PAN:HPMC nanofiber membranes, as confirmed by scanning electron microscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) measurements. The Gr content has a significant impact on the diameter, porosity, and pore size. The PAN:HPMC:0.02Gr electrospun nanofiber membranes achieved excellent oil rejection (72.47%) and good permeability flux (750 LMH); this might be a result of how well the functional groups of the equally distributed Gr within the PAN:HPMC nanofibers interacted with oil. It was noticed that oil rejection dropped a lot as the Gr content went up. This is likely because the pores got wider and some of the Gr stacked or agglomerated across the nanofibers.
Received: Jul. 27, 2023
Revised: Dec. 21, 2023
Accepted: Dec. 24, 2023
Article Details
This work is licensed under a Creative Commons Attribution 4.0 International License.
© 2023 The Author(s). Published by College of Science, University of Baghdad. This is an open-access article distributed under the terms of the Creative Commons Attribution 4.0 International License.
References
B. Barua and M. C. Saha, J. Appl. Poly. Sci. 132, 41918 (2015).
H. S. Al-Okaidy and B. I. Waisi, Baghdad Sci. J. 20, 1433 (2023).
Z. Zhao, J. Zheng, M. Wang, H. Zhang, and C. C. Han, J. Memb. Sci. 394, 209 (2012).
H. M. Hawy and I. M. Ali, Optik 262, 169263 (2022).
S. Faraji, M. F. Yardim, D. S. Can, and A. S. Sarac, J. Appl. Poly. Sci. 134, 44381 (2017).
S. Alkarbouly and B. Waisi, Proceedings of 2nd International Multi-Disciplinary Conference (Sakarya, Turkey EAI, 2022). p.
J. Zhang, X. Pan, Q. Xue, D. He, L. Zhu, and Q. Guo, J. Membr. Sci. 532, 38 (2017).
H. Yan, H. Wu, K. Li, Y. Wang, X. Tao, H. Yang, A. Li, and R. Cheng, ACS Appl. Mat. Inter. 7, 6690 (2015).
A. A. Muhammad and I. M. Ibrahim, Neuro. Quant. 20, 1984 (2022).
D. Chen, H. Feng, and J. Li, Chem. Rev. 112, 6027 (2012).
H. M. Hawy and I. M. Ali, Optik 267, 169659 (2022).
N. M. Aboamera, A. Mohamed, A. Salama, T. Osman, and A. Khattab, Mech. Advan. Mat. Struct. 26, 765 (2019).
Y. Gao, J. Qin, Z. Wang, and S. W. Østerhus, J. Membr. Sci. 587, 117136 (2019).
S. M. Alardhi, F. Y. Aljaberi, and L. M. Alsaedi, Egyptian J. Chem. 63, 4963 (2020).
K. Venkatesh, G. Arthanareeswaran, A. C. Bose, P. S. Kumar, and J. Kweon, Sep. Purific. Tech. 257, 117926 (2021).
H. Oliveira, A. Azevedo, R. Etchepare, and J. Rubio, Water Sci. Tech. 76, 2710 (2017).
A. A. Abdel-Aty, Y. S. A. Aziz, R. M. Ahmed, I. M. Elsherbiny, S. Panglisch, M. Ulbricht, and A. S. Khalil, Sep. Purific. Tech. 253, 117467 (2020).
M. Kadhom, K. Kalash, and M. Al-Furaiji, Chemosphere 290, 133256 (2022).
M. S. Islam, A. N. Naz, M. N. Alam, A. K. Das, and J. H. Yeum, Coll. Inter. Sci. Commun. 35, 100247 (2020).
J. C. Ge, G. Wu, S. K. Yoon, M. S. Kim, and N. J. Choi, Nanomaterials 11, 2514 (2021).
I. Karbownik, O. Rac-Rumijowska, M. Fiedot-Toboła, T. Rybicki, and H. Teterycz, Materials 12, 664 (2019).
S. Nithya, S. Selvasekarapandian, and M. Premalatha, Ionics 23, 2767 (2017).
S. Huang, R. H. Ras, and X. Tian, Curr. Opin. Coll. Inter. Sci. 36, 90 (2018).
M. L. Hassan, S. M. Fadel, R. E. Abouzeid, W. S. Abou Elseoud, E. A. Hassan, L. Berglund, and K. Oksman, Sci. Rep. 10, 11278 (2020).
M. Shakiba, S. R. Nabavi, H. Emadi, and M. Faraji, Poly. Advan. Tech. 32, 1301 (2021).
N. S. A. Rahman, M. F. Yhaya, B. Azahari, and W. R. Ismail, Cellulose 25, 4887 (2018).
X. Wang, J. Yu, G. Sun, and B. Ding, Mat. Today 19, 403 (2016).
M. Faccini, G. Borja, M. Boerrigter, D. M. Martín, S. M. Crespiera, S. Vázquez-Campos, L. Aubouy, and D. Amantia, J. Nanomat. 2015, 2 (2015).
S. Liu, M. Kok, Y. Kim, J. L. Barton, F. R. Brushett, and J. Gostick, J. Electrochem. Soci. 164, A2038 (2017).
W. Chen, Y. Su, L. Zheng, L. Wang, and Z. Jiang, J. Membr. Sci. 337, 98 (2009).
Z. L. Kiss, S. Kertész, S. Beszédes, C. Hodúr, and Z. László, Desalin. Water Treat. 51, 4914 (2013).
S. Ali, Z. Khatri, K. W. Oh, I.-S. Kim, and S. H. Kim, Macromol. Res. 22, 562 (2014).
J. Fu, D. Li, G. Li, F. Huang, and Q. Wei, J. Electroanal. Chem. 738, 92 (2015).
N. Hembach, J. Alexander, C. Hiller, A. Wieland, and T. Schwartz, Sci. Rep. 9, 12843 (2019).
J. Lee, J. Yoon, J. H. Kim, T. Lee, and H. Byun, J. Appl. Poly. Sci. 135, 45858 (2018).
C. Liao, X.-R. Zhao, X.-Y. Jiang, J. Teng, and J.-G. Yu, Microchem. J. 152, 104288 (2020).
W. Jang, Y. Park, C. Park, Y. Seo, J.-H. Kim, J. Hou, and H. Byun, J. Membr. Sci. 598, 117670 (2020).
N. Kumar and V. C. Srivastava, ACS Omega 3, 10233 (2018).
M. A. Akaood, B. I. Waisi, and I. M. Ali, Iraqi J. Appl. Phys. 20, 71 (2024).
M. Al-Furaiji, J. T. Arena, J. Ren, N. Benes, A. Nijmeijer, and J. R. Mccutcheon, Membranes 9, 60 (2019).
Q. Wang, J. Cui, S. Liu, J. Gao, J. Lang, C. Li, and Y. Yan, J. Mat. Sci. 54, 8332 (2019).
B. L. Abbood, K. A. Sukkar, and J. A. Al-Najar, J. Appl. Sci. Nanotech. 1, 91 (2021).
A. H. Mohsan and N. A. Ali, Iraqi J. Phys. 20, 14 (2022).
A. Almasian, M. Giahi, G. C. Fard, S. Dehdast, and L. Maleknia, Chem. Eng. J. 351, 1166 (2018).
L. Deng, P. Li, K. Liu, X. Wang, and B. S. Hsiao, J. Mat. Chem. A 7, 11282 (2019).
J. H. Li, H. Zhang, W. Zhang, and W. Liu, J. Biomat. Sci. Poly. Ed. 30, 1620 (2019).
N. Naseeb, A. A. Mohammed, T. Laoui, and Z. Khan, Materials 12, 212 (2019).
E. Mahmoudi, L. Y. Ng, W. L. Ang, Y. T. Chung, R. Rohani, and A. W. Mohammad, Sci. Rep. 9, 1216 (2019).
Z.-Z. Yang, Q.-B. Zheng, H.-X. Qiu, J. Li, and J.-H. Yang, N. Carb. Mat. 30, 41 (2015).
Z. Wang, A. Wu, L. Colombi Ciacchi, and G. Wei, Nanomaterials 8, 65 (2018).